Methyl acetate CAS#79-20-9

  • CAS Number: 79-20-9

  • Chemical Formula:C3H6O2

  • Synonyms:

    • methyle(acetatede)(french)

    • methylethanoate

    • Acetate de methyle

    Appearance: Clear colorless to slightly pale yellow Liquid

  • MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)


Product Details

Methyl acetate CAS#79-20-9


Methyl acetate, also known as MeOAc , acetic acid methyl ester or methyl ethanoate, is a carboxylate ester with the formula CH3COOCH3. It is a flammable liquid with a characteristically pleasant smell reminiscent of some glues and nail polish removers. Methyl acetate is occasionally used as a solvent, being weakly polar and lipophilic, but its close relative ethyl acetate is a more common solvent being less toxic and less soluble in water. Methyl acetate has a solubility of 25% in water at room temperature. At elevated temperature its solubility in water is much higher. Methyl acetate is not stable in the presence of strong aqueous bases or aqueous acids. Methyl acetate is VOC exempt.


Methyl acetate Chemical Properties

Melting point 

-98 °C (lit.)

Boiling point 

57-58 °C (lit.)

density 

0.934 g/mL at 25 °C

vapor density 

2.55 (vs air)

vapor pressure 

165 mm Hg ( 20 °C)

refractive index 

n20/D 1.361(lit.)

FEMA 

2676 | METHYL ACETATE

Fp 

3.2 °F

storage temp. 

no restrictions.

solubility 

250g/l

form 

Solution

color 

Clear colorless to slightly pale yellow

Relative polarity

0.253

Odor

Slightly acrid, sweet; fragrant.

PH

7

biological source

synthetic

Odor Threshold

1.7ppm

Odor Type

ethereal

explosive limit

3.1-16%(V)

Water Solubility 

250 g/L (20 ºC)

λmax

λ: 255 nm Amax: 1.0
λ: 275 nm Amax: 0.1
λ: 300 nm Amax: 0.01

Merck 

14,6008

JECFA Number

125

BRN 

1736662

Henry's Law Constant

0.90 at 20.00 °C, 1.56 at 30.00 °C (headspace-GC, Hovorka et al., 2002)

Exposure limits

TLV-TWA 200 ppm (~610 mg/m3) (ACGIH, MSHA, and OSHA); TLV-STEL 250 ppm (~760 mg/m3) (ACGIH); IDLH 10,000 ppm (NIOSH).

Dielectric constant

7.3(20℃)

Stability:

Stable. Extremely flammable - readily forms explosive mixtures with air. Note low flash point and wide explosion limits. Incompatible with strong oxidizing agents, strong bases, strong acids, nitrates. May be moisture sensitive.

Cosmetics Ingredients Functions

PERFUMING
SOLVENT

LogP

0.18 at 20℃

Surface tension

25.4mN/m at 298.15K

CAS DataBase Reference

79-20-9(CAS DataBase Reference)

NIST Chemistry Reference

Acetic acid, methyl ester(79-20-9)

EPA Substance Registry System

Methyl acetate (79-20-9)


Safety Information

Hazard Codes 

F,Xi

Risk Statements 

11-36-66-67

Safety Statements 

16-26-29-33

OEB

A

OEL

TWA: 200 ppm (610 mg/m3), STEL: 250 ppm (760 mg/m3)

RIDADR 

UN 1231 3/PG 2

WGK Germany 

1

RTECS 

AI9100000

Autoignition Temperature

936 °F

TSCA 

Yes

HS Code 

2915 39 00

HazardClass 

3

PackingGroup 

II

Hazardous Substances Data

79-20-9(Hazardous Substances Data)

Toxicity

LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rat > 2000 mg/kg

IDLA

3,100 ppm [10% LEL]


Product Application of Methyl acetate CAS#79-20-9


Methyl acetate may be used for the preparation of fatty acid methyl esters and triacetin from rapeseed oil via non-catalytic trans-esterification reaction under super-critical conditions.
Methyl acetate may be used in the following:
As acyl acceptor in the preparation of biodiesel.
Synthesis of ethanol.
Preparation of n-butyl acetate, via transesterification reaction with n-butanol in the presence of acidic catalysts.
It may also be used as a precursor in the synthesis of the following:
acetic anhydride
methyl acrylate
vinyl acetate


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