Methanol CAS#67-56-1

  • CAS Number: 67-56-1

  • Chemical Formula: CH4O

  • Synonyms:

    • METHYL RED MIXED SOLUTION

    • METHYL RED, NEUTRAL

    • METHYL RED, WATER SOLUBLE

    Appearance: Transperant Liquid

  • MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)


Product Details

Methanol CAS#67-56-1

Methanol is the simplest fatty alcohol. It is a colorless, flammable, irritating liquid with a boiling point of 64.7°C, a melting point of -93.90°C, and a relative density of 0.7913. Soluble in water and most organic solvents. Its severe toxicity can damage the optic nerve. Once swallowed, it can make the eyes blind and even cause death.
Methanol has the general properties of a primary aliphatic alcohol. The three hydrogen atoms on a carbon atom with a hydroxyl group can be oxidized, orderly generating formaldehyde, formic acid, and carbon dioxide. Therefore, it is largely used in the synthesis of formaldehyde. Methanol is easily converted into important organic synthesis intermediates such as methyl carboxylate, methyl chloride and methylamine, and it is also applied as important organic solvents, extraction agents and alcohol denaturants.

Methanol Chemical Properties

Melting point 

-98 °C(lit.)

Melting point 

-97,8°C

Boiling point 

64,7°C

Boiling point 

65.4 °C(lit.)

density 

0.791 g/mL at 25 °C

density 

d = 0,89

vapor density 

1.11 (vs air)

vapor pressure 

410 mm Hg ( 50 °C)

refractive index 

n20/D 1.329(lit.)

Fp 

52 °F

storage temp. 

2-8°C

solubility 

benzene: miscible(lit.)

form 

Liquid Free From Particulates

pka

15.2(at 25℃)

Specific Gravity

0.793 (20/20℃)

color 

<10(APHA)

PH

6.8 (20°C in H2O)

Relative polarity

0.762

Flame Color

Pale blue

Odor

Faint alcohol odor detectable at 4 to 6000 ppm (mean = 160 ppm)

Odor Threshold

33ppm

explosive limit

5.5-44%(V)

Water Solubility 

miscible

λmax

λ: 210 nm Amax: 0.50
λ: 220 nm Amax: 0.30
λ: 230 nm Amax: 0.15
λ: 235 nm Amax: 0.10
λ: 240 nm Amax: 0.05
λ: 260 nm Amax: 0.01
λ: 400 nm Amax: 0.01

Merck 

14,5957

BRN 

1098229

Henry's Law Constant

4.99 at 25 °C (headspace-GC, Gupta et al., 2000)

Exposure limits

TLV-TWA (200 ppm) (ACGIH), 260mg/m3, 1040mg/m3 (800 ppm) 15minutes (NIOSH); STEL 310mg/m3 (250 ppm); IDLH 25,000 ppm (NIOSH).

Dielectric constant

33.6(20℃)

Cosmetics Ingredients Functions

SOLVENT
FRAGRANCE
DENATURANT

InChI

1S/CH4O/c1-2/h2H,1H3

InChIKey

OKKJLVBELUTLKV-UHFFFAOYSA-N

SMILES

CO

LogP

-0.770

Surface tension

22.22mN/m at 298.15K

Surface tension

22.7mN/m at 20°C

CAS DataBase Reference

67-56-1(CAS DataBase Reference)

NIST Chemistry Reference

Methyl alcohol(67-56-1)

EPA Substance Registry System

Methanol (67-56-1)

Absorption

in accordance


Safety Information

Hazard Codes 

Xn,T,F

Risk Statements 

10-20/21/22-68/20/21/22-39/23/24/25-23/24/25-11-40-36-36/38-23/25

Safety Statements 

36/37-7-45-16-24/25-23-24-26

RIDADR 

UN 1170 3/PG 2

OEB

A

OEL

TWA: 200 ppm (260 mg/m3), STEL: 250 ppm (325 mg/m3) [skin]

WGK Germany 

1

RTECS 

PC1400000

3-10

Autoignition Temperature

385 °C

TSCA 

TSCA listed

HS Code 

2905 11 00

HazardClass 

3

PackingGroup 

II

Storage Class

3 - Flammable liquids

Hazard Classifications

Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Flam. Liq. 2
STOT SE 1

Hazardous Substances Data

67-56-1(Hazardous Substances Data)

Toxicity

LD50 oral (rat)
5628 mg/kg
LD50 skin (rabbit)
15,840 mg/kg
LC50 inhal (rat)
>145,000 ppm (1 h)
PEL (OSHA)
200 ppm (260 mg/m3)
TLV-TWA (ACGIH)
200 ppm (260 mg/m3)—skin
STEL (ACGIH)
250 ppm (328 mg/m3)

IDLA

6,000 ppm


Product Application Of Methanol CAS#67-56-1

Methylalcohol, CH30H, also known as methanol or wood alcohol, is a colorless, toxic, flammable liquid with a boiling point of 64.6 °C(147 °F). The principal toxic effect is on the nervous system,particularly the retinae. Methyl alcoholis miscible in all proportions with water,ethyl alcohol, and ether. It burns with a light blue flame producing water and carbon dioxide. This vapor forms an explosive mixture(6.0 to 36.5% by volume) with air. Methyl alcohol is an important inexpensive raw material that is synthetically produced for the organic chemical industry. Nearly half of the methyl alcohol manufactured is used in the production of formaldehyde. Other uses of methyl alcohol are as an antifreeze and fuel for automobiles and as an intermediate in the production of synthetic protein.

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