Tetrahydrothiophene CAS#:110-01-0

  • CAS Number: 110-01-0

  • Chemical FormulaC4H8S

  • Synonyms:

    • TETRAHYDROTHIOPHENE

    • TETRAHYDROTHIOPHEN 99%(GC)

    • thiophane

  • Appearance: Colorless liquid

  • HS Code: 29349990

  • MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)


Product Details

Products Description of Tetrahydrothiophene CAS#:110-01-0

Tetrahydrothiophene is cyclic thioalkane, namely, saturated analog of thiophene. It is a colorless transparent volatile liquid, insoluble in water, miscible in ethanol, ether, benzene, acetone. It has a strong unpleasant odor, is stable and not easily emitted, and can be smelled in the air at 0.01PPm. It is not corrosive to gas equipment, transportation pipeline gaskets and other materials, and does not produce habitual blunting of the human sense of smell, so it is used as an odorant in LPG and natural gas, outlawing the original use of ethyl mercaptan and other odor-assigning agents.

Tetrahydrothiophene Chemical Properties
Melting point -96 °C (lit.)
Boiling point 119 °C (lit.)
density 1 g/mL at 25 °C (lit.)
vapor pressure 18 mm Hg ( 25 °C)
refractive index n20/D 1.504(lit.)
Fp 55 °F
storage temp. Store below +30°C.
solubility immiscible
form liquid
Specific Gravity1.002 (20/4℃)
color Colorless to Almost colorless
OdorSmells of rotting eggs
PH7 (H2O, 20℃)
explosive limit1.1-12.1%(V)
Odor Threshold0.00062ppm
Odor Typesulfurous
Water Solubility immiscible
Merck 14,9218
BRN 102392
Dielectric constant8.6099999999999994
Stability:Highly flammable. Vapour-air mixtures explosive in some proportions; note low flash point and fairly wide explosion limit range. Heavier than air, so potentially explosive mixtures may travel considerable distances to source of ignition.
LogP1.8 at 20℃
CAS DataBase Reference110-01-0(CAS DataBase Reference)
NIST Chemistry ReferenceThiophene, tetrahydro-(110-01-0)
EPA Substance Registry SystemTetrahydrothiophene (110-01-0)

Safety Information
Hazard Codes F,Xn
Risk Statements 11-20/21/22-36/38-52/53
Safety Statements 16-23-36/37-61
RIDADR UN 2412 3/PG 2
WGK Germany 2
RTECS XN0370000
Autoignition Temperature202 °C
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29349990
Hazardous Substances Data110-01-0(Hazardous Substances Data)
ToxicityLD50 by inhalation in mice: 26.7 mg/l (Carlucci)

Product Application of Tetrahydrothiophene CAS#:110-01-0

Tetrahydrothiophene is a solvent and a fuel gas odorant used in fire safety stench warning systems in underground mines. Tetrahydrothiophene was also used as an organocatalyst for the reaction between enynediones and benzoic acid to afford highly substituted furfuryl alcohol benzoates.

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