Tributyl phosphate CAS#126-73-8

  • CAS Number:  126-73-8

  • Chemical Formula: C12H27O4P

  • Synonyms:

    • Phosphoric acid tributyl

    • Tributyl phosphate  5g [126-73-8]

    • Tributyl phosphate  10g [126-73-8]

    Appearance: Transperant Liquid

  • MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)


Product Details

Tributyl phosphate CAS#126-73-8

Tributyl phosphate (126-73-8);is an odorless colorless to yellow liquid. The solubility of TBP is only 280 mg/L in water at 25°C. It is soluble in diethyl ether, benzene, carbon disulfide. It can be miscible with ethanol. It is stable, but it is incompatible with strong oxidizing agents.
Tributyl phosphate
Tributyl phosphate (TBP) is an organophosphorus compound widely used as a solvent in nuclear fuel reprocessing for the extraction of uranium and plutonium from other radionuclides.
The major uses of tributyl phosphate (TBP) in industry are as a flame retardant component of aircraft hydraulic fluid and as a solvent for rare earth extraction and purification. Minor uses of TBP include use as a defoamer additive in cement casings for oil wells, as an anti-air entrainment additive for coatings and floor finishes, as a solvent in nuclear fuel processing, and as a carrier for fluorescent dyes.
The microbial degradation of tributyl phosphate was carried out using Klebsiella pneumoniae S3 isolated from the soil. The solubilization behavior of TBP in aqueous solutions of L64-Pluronics was studied using light and small angle neutron scattering (SANS).

Tributyl phosphate Chemical Properties

Melting point 

-79 °C (lit.)

Boiling point 

180-183 °C/22 mmHg (lit.)

density 

0.979 g/mL at 25 °C (lit.)

vapor density 

9.2 (vs air)

vapor pressure 

27 mm Hg ( 178 °C)

refractive index 

n20/D 1.424(lit.)

Fp 

380 °F

storage temp. 

Store below +30°C.

solubility 

water: soluble1ml in 165ml water

form 

Liquid

color 

Clear

Odor

Odorless

Water Solubility 

0.6 g/100 mL

Merck 

14,9618

BRN 

1710584

Exposure limits

TLV-TWA 2.18 mg/m3 (0.2 ppm) (ACGIH), 5 mg/m3 (OSHA and NIOSH); IDLH 1300 mg/m3 (120 ppm) (NIOSH).

Dielectric constant

6.5(20℃)

Stability:

Stable. Combustible. Incompatible with strong oxidizing agents. May be water sensitive.

LogP

4 at 20℃

Surface tension

27.2mN/m at 298.15K

CAS DataBase Reference

126-73-8(CAS DataBase Reference)

NIST Chemistry Reference

Tri-n-butylphosphate(126-73-8)

EPA Substance Registry System

Tributyl phosphate (126-73-8)


Safety Information

Hazard Codes 

Xn,F

Risk Statements 

22-38-40-62-48/20-36/37/38-11-20/22

Safety Statements 

36/37-46-45-36/37/39-16-53

RIDADR 

UN 1208 3/PG 2

OEB

B

OEL

TWA: 0.2 ppm (2.5 mg/m3)

WGK Germany 

2

RTECS 

TC7700000

Autoignition Temperature

770 °F

TSCA 

TSCA listed

HS Code 

29190010

Hazardous Substances Data

126-73-8(Hazardous Substances Data)

Toxicity

LD50 orally in rats: 3.0 g/kg (Smyth, Carpenter)

IDLA

30 ppm


Product Application of Tributyl phosphate CAS#126-73-8

Tributyl phosphate (TBP,126-73-8) is a trialkyl phosphate that is the tributyl ester of phosphoric acid. TBP is a toxic organophosphorous compound widely used in many industrial applications, including significant usage in nuclear processing. TBP is a solvent and plasticizer for cellulose esters such as nitrocellulose and cellulose acetate. The major uses of TBP in industry are as a component of aircraft hydraulic fluid and as a solvent for extraction and purification of rare earth metals from their ores, such as uranium and plutonium. TBP is used also in mercerizing liquids, where it improves their wetting properties. TBP is also used as a heat exchange medium. TBP is used in some consumer products such as herbicides and water thinned paints and tinting bases.


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