BENZENESULFINIC ACID SODIUM SALT CAS#873-55-2
CAS Number: 873-55-2
Chemical Formula: C6H5NaO2S
Synonyms:
4-CHLOROBENZENESULPHINIC ACID SODIUM SALT
BENZENESULFINIC ACID NA SALT
Benzenesulfinic acid sodium salt
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)
Appearance: White Powder
BENZENESULFINIC ACID SODIUM SALT CAS#873-55-2
Benzenesulfinic acid sodium salt when treated with alkynylselenonium salts yields (Z)-β-alkoxyvinylsulfones. It undergoes rhodium-catalyzed desulfinative coupling with aldehydes to yield ketones.
BENZENESULFINIC ACID SODIUM SALT Chemical Properties |
Melting point | >300 °C(lit.) |
Boiling point | 83-84 °C |
density | 1.45[at 20℃] |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Water |
form | Crystals or Crystalline Powder |
color | White |
Water Solubility | Soluble in water. |
Sensitive | Hygroscopic |
BRN | 3598405 |
InChI | InChI=1S/C6H6O2S.Na/c7-9(8)6-4-2-1-3-5-6;/h1-5H,(H,7,8);/q;+1/p-1 |
InChIKey | CHLCPTJLUJHDBO-UHFFFAOYSA-M |
SMILES | [Na+].C1(S([O-])=O)=CC=CC=C1 |
LogP | -3.54 |
CAS DataBase Reference | 873-55-2(CAS DataBase Reference) |
EPA Substance Registry System | Benzenesulfinic acid, sodium salt (873-55-2) |
Safety Information |
Hazard Codes | Xi,Xn |
Risk Statements | 36/37/38-20/21/22 |
Safety Statements | 26-37/39-36-24/25 |
WGK Germany | 1 |
RTECS | DA9135000 |
TSCA | TSCA listed |
HS Code | 29309090 |
Storage Class | 11 - Combustible Solids |
Product Application Of BENZENESULFINIC ACID SODIUM SALT CAS#873-55-2
Benzenesulfinic acid sodium salt has been used in synthesis of sulfones by reaction of organic halides and sodium benzenesulfinate using higher alcohols or diols as solvents.It was also used in the synthesis of aryl sulfones via copper-catalyzed cross-coupling with boronic acids and vinyl sulfones via reaction with vicinal dibromides.
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