4,4'-Diphenylmethane diisocyanate CAS#101-68-8
CAS Number: 101-68-8
Chemical Formula: C15H10N2O2
Synonyms:
1,1’-methylenebis(4-isocyanato)-benzene;para
para’-diphenylmethanediisocyanate;para
METHYLENEDIPHENYL 4,4'-DIISOCYANATE
Appearance: White power
HS Code: 29291090
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)
Products Description of 4,4'-Diphenylmethane diisocyanate
Light yellow molten solid with a strong irritating odor. Soluble in acetone, benzene, kerosene and nitrobenzene.
Parameters
| Melting point | 38-44 °C |
| Boiling point | 392 °C |
| density | 1.19 |
| vapor pressure | 0.066 hPa (20 °C) |
| refractive index | 1.5906 (estimate) |
| Fp | 196 °C |
| storage temp. | -20°C |
| solubility | 2g/l (decomposition) |
| form | solid |
| color | White to Almost white |
| Specific Gravity | 1.180 |
| explose limit | 0.4%(V) |
| Water Solubility | decomposes |
| FreezingPoint | 37℃ |
| Sensitive | Moisture Sensitive/Lachrymatory |
| BRN | 797662 |
| Exposure limits | TLV-TWA 0.051 mg/m3 (0.005 ppm) (ACGIH and NIOSH); ceiling (air) 0.204 mg/m3 (0.02 ppm)/10 min (NIOSH and OSHA); IDLH 102 mg/m3 (10 ppm). |
| Dielectric constant | 10.0(Ambient) |
| Stability: | Stable. Combustible. Incompatible with strong oxidizing agents. Reacts violently with alcohols. |
| CAS DataBase Reference | 101-68-8(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzene, 1,1'-methylenebis[4-isocyanato-(101-68-8) |
| IARC | 3 (Vol. 19, Sup 7, 71) 1999 |
| EPA Substance Registry System | 4,4'-Methylenedi(phenyl isocyanate) (101-68-8) |
Safety Information
| Hazard Codes | Xn,T,C |
| Risk Statements | 42/43-36/37/38-20-48/20-40 |
| Safety Statements | 45-36/37-23 |
| RIDADR | 2206 |
| OEB | D |
| OEL | TWA: 0.05 mg/m3 (0.005 ppm), Ceiling: 0.2 mg/m3 (0.020 ppm) [10-minute] |
| WGK Germany | 1 |
| RTECS | NQ9350000 |
| Autoignition Temperature | >600 °C |
| Hazard Note | Toxic/Corrosive/Lachrymatory/Moisture Sensitive |
| TSCA | Yes |
| HazardClass | 6.1 |
| PackingGroup | II |
| HS Code | 29291090 |
| Hazardous Substances Data | 101-68-8(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 9000 mg/kg |
| IDLA | 75 mg/m3 |
Product Application of 4,4'-Diphenylmethane diisocyanate
Cyanide, isocyanate and its derivatives; polyurethane materials; organic blocks; organic chemical raw materials; chemical products - organic chemistry; isocyanate ester; organic compounds; chemistry; chemical raw materials; Diphenylmethanes(forHigh-PerformancePolymerResearch); FunctionalMateriaChemicalbookls; ReagentforHigh-PerformancePolymerResearch; Alphabetic; M; META-METH; Analyze the standard samples; Pyridines,HalogenatedHeterocycles; New material synthesis raw materials; Organic raw materials; Basic raw materials; Additives.
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