Phenylhydrazine CAS#100-63-0

CAS Number: 100-63-0
Chemical Formula: C6H8N2
Synonyms:

1-Hydrazinobenzene
Phenyl hydrazide
Phenylhydrazine,95%

Appearance: White Powder

MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

Contact Now E-Mail Telephone WhatsApp

Product Details

Phenylhydrazine CAS#100-63-0

Pale yellow crystals. Melting point 66°F. Becomes an oily liquid. Toxic by ingestion, inhalation and skin absorption. Flash point 192°F. Autoignition temperature 345°F. Soluble in alcohol.

Phenylhydrazine Chemical Properties

Melting point	18-21 °C (lit.)
Boiling point	238-241 °C (lit.)
density	1.098 g/mL at 25 °C (lit.)
vapor density	4.3 (vs air)
vapor pressure	<0.1 mm Hg ( 20 °C)
refractive index	n20/D 1.607(lit.)
Fp	192 °F
storage temp.	Store below +30°C.
solubility	Soluble in dilute acids.
form	Powder
pka	8.79(at 15℃)
color	White to slightly blue or light beige
explosive limit	1.1%(V)
Water Solubility	145 g/L (20 ºC)
Sensitive	Air & Light Sensitive
Merck	14,7293
BRN	606080
Dielectric constant	7.2（23℃）
Exposure limits	TLV-TWA skin 0.1 ppm (0.44 mg/m3) (ACGIH), 5 ppm (22 mg/m3) (OSHA); STEL 10 ppm (44 mg/m3) (OSHA); carcinogenicity: A2-Suspected Human Carcinogen (ACGIH), Carcinogen (NIOSH). .
Stability:	Stable, but may decompose in sunlight. May be air or light sensitive. Incompatible with strong oxidizing agents, metal oxides.
InChI	1S/C6H8N2/c7-8-6-4-2-1-3-5-6/h1-5,8H,7H2
InChIKey	HKOOXMFOFWEVGF-UHFFFAOYSA-N
SMILES	NNc1ccccc1
CAS DataBase Reference	100-63-0(CAS DataBase Reference)
NIST Chemistry Reference	Hydrazine, phenyl-(100-63-0)
EPA Substance Registry System	Phenylhydrazine (100-63-0)

Safety Information

Hazard Codes	T,N
Risk Statements	45-23/24/25-36/38-43-48/23/24/25-50-68
Safety Statements	53-45-61
RIDADR	UN 2572 6.1/PG 2
OEL	Ceiling: 0.14 ppm (0.6 mg/m3) [2-hr] [skin]
WGK Germany	3
RTECS	MV8925000
F	8-10-23
Autoignition Temperature	345 °F
TSCA	TSCA listed
HS Code	2928 00 90
HazardClass	6.1
PackingGroup	II
Storage Class	6.1A - Combustible, acute toxic Cat. 1 and 2 very toxic hazardous materials
Hazard Classifications	Acute Tox. 3 Dermal Acute Tox. 3 Inhalation Acute Tox. 3 Oral Aquatic Acute 1 Carc. 1B Eye Irrit. 2 Muta. 2 Skin Irrit. 2 Skin Sens. 1 STOT RE 1
Hazardous Substances Data	100-63-0(Hazardous Substances Data)
Toxicity	LD50 orally in Rabbit: 188 mg/kg
IDLA	15 ppm

Product Application Of Phenylhydrazine CAS#100-63-0

Phenylhydrazine is the first synthetic hydrazine derivatives which can often be used as intermediates of organic dyes, pharmaceuticals and pesticide. It can also be used as organic intermediates for synthesis of pyrazoline, triazole, and indole; It can also be used as dye intermediates like disazo dye intermediates such as 1-phenyl-3-methyl-5-pyrazolone and so on; It can also be used as pharmaceutical intermediates for preparation of antipyretic, analgesic, anti-inflammatory drugs such as antipyrine and aminopyrine, etc; it can also be used as photography drugs (photosensitive dye); phenylhydrazine is also the raw material for the production of pesticides "imputed phosphorus"; phenylhydrazine is also an important kind of carbonyl group identification reagents used for identifying aldehydes, ketones and carbohydrates.
Phenylhydrazine is toxic. After inhalation, due to hemolysis, it can cause anemia and headache and can even cause jaundice in severe cases. It can also have stimulating effect on the eyes such as causing corneal disorders. Rat-oral LD50:188 mg/kg. Workplace: maximum allowable concentration: 0.44mg/m3.
Lab often uses aniline as raw materials for reaction with sodium nitrite in hydrochloric acid for generating diazonium salt and then reacted with sulfur dioxide and sulfurous acid for reduction to produce phenylhydrazine sodium sulfonate and further salting via hydrochloric acid to form phenylhydrazine hydrochloride. After neutralization and deacidification, we can obtain phenylhydrazine.

Factory and Equipment Show

Gardenia Yellow#94238-00-3