Tetrabutylammonium perchlorate CAS#1923-70-2

CAS Number: 1923-70-2
Chemical Formula: C16H36ClNO4
Synonyms:

TETRABUTYLAMMONIUM PERCHLORATE ELECTRO-C HEMICAL GRADE
TetrabutylaMMoniuM Perchlorate, 98.0%(T)
tetrabutylazanium,perchlorate (TBAP)

Appearance: White Powder

MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

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Product Details

Tetrabutylammonium perchlorate CAS#1923-70-2

Crystallise the perchlorate from EtOH ethyl acetate, from n-hexane or diethyl ether/acetone mixture, ethyl acetate or hot CH2Cl2. Dry it in a vacuum at room temperature over P2O5 for 24hours. [Anson et al. J Am Chem Soc 106 4460 1984, Ohst & Kochi J Am Chem Soc 108 2877 1986, Collman et al. J Am Chem Soc 108 2916 1986, Blau & Espenson J Am Chem Soc 108 1962 1986, Gustowski et al. J Am Chem Soc 108 1986, Ikezawa & Kutal J Org Chem 52 3299 1987, Beilstein 4 IV 557.]

Tetrabutylammonium perchlorate Chemical Properties

Melting point	211-215 °C
density	1.0387 (rough estimate)
refractive index	1.6800 (estimate)
storage temp.	2-8°C, sealed storage, away from moisture
solubility	acetonitrile: 0.1 g/mL, clear, colorless
form	Crystalline Powder
color	White
Water Solubility	Soluble in acetonitrile and ethanol. Very slightly soluble in water.
Sensitive	Hygroscopic
BRN	3579274
Stability:	Stable. Strong oxidizer - contact with combustible material may cause fire. Incompatible with strong reducing agents, combustible materials. Do not heat.
InChI	InChI=1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
InChIKey	KBLZDCFTQSIIOH-UHFFFAOYSA-M
SMILES	[N+](CCCC)(CCCC)(CCCC)CCCC.Cl([O-])(=O)(=O)=O
CAS DataBase Reference	1923-70-2(CAS DataBase Reference)
EPA Substance Registry System	1-Butanaminium, N,N,N-tributyl-, perchlorate (1923-70-2)

Safety Information

Hazard Codes	O,Xi
Risk Statements	5-8-36/37/38
Safety Statements	17-26-36-36/37/39
RIDADR	UN 1479 5.1/PG 2
WGK Germany	3
TSCA	TSCA listed
HazardClass	5.1
PackingGroup	II
HS Code	29239000
Storage Class	5.1B - Oxidizing hazardous materials
Hazard Classifications	Eye Irrit. 2 Ox. Sol. 2 Skin Irrit. 2 STOT SE 3

Tetrabutylammonium perchlorate CAS#1923-70-2

Suitable for use as a polarographic supporting electrolyteTetra-n-butylammonium perchlorate is used as a supporting electrolyte in polarographic measurements.

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