DimethoxymethaneCAS#109-87-5
Chemical Name:Dimethoxymethane
CAS No.:109-87-5
Appearance: Clear colorless Liquid
Molecular Formula:C3H8O2
Molecular weight:76.09
Sample: Available
Products Description of Methylal CAS#109-87-5
Methylal industrial product purity ≥ 99%, colorless transparent liquid, with chloroform-like odor. Melting point -105℃, boiling point 42.3℃. Vapor pressure 364.57 mmHg (25℃), relative density 0.86 (20℃). Solubility in water: 32.3 g/100mL (16℃), miscible with most organic solvents. Stable but highly flammable, incompatible with strong oxidizing agents and acids.
Parameters
Melting point | -105 °C |
Boiling point | 41-43 °C |
density | 0.860 g/mL at 20 °C(lit.) |
vapor density | 2.6 (vs air) |
vapor pressure | 6.38 psi ( 20 °C) |
refractive index | n |
Fp | -18 °C |
storage temp. | Store at <= 20°C. |
solubility | 32.3 g/100 mL (16°C) |
pka | 3.1[at 20 ℃] |
form | Liquid |
color | Clear colorless |
Odor | Mild, ethereal; chloroform-like. |
PH | pH (12.5vol % , 25℃) : 4.5~6.6 |
explosive limit | 1.6-17.6%(V) |
Water Solubility | 32.3 g/100 mL (16 ºC) |
Sensitive | Moisture Sensitive |
Merck | 14,6012 |
BRN | 1697025 |
Henry's Law Constant | (x 10-4 atm?m3/mol): 1.73 at 25 °C (Hine and Mookerjee, 1975) |
Dielectric constant | 2.7(20℃) |
Exposure limits | NIOSH REL: TWA 1,000 ppm (3,100 mg/m3), IDLH 2,200 ppm; OSHA PEL: TWA 1,000 ppm; ACGIH TLV: TWA 1,000 ppm (adopted). |
Stability: | Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point and wide explosive limits. Incompatible with strong oxidizing agents, strong acids. May form explosive peroxides upon exposure to air. |
LogP | 0 |
CAS DataBase Reference | 109-87-5(CAS DataBase Reference) |
NIST Chemistry Reference | Methane, dimethoxy-(109-87-5) |
EPA Substance Registry System | Dimethoxymethane (109-87-5) |
Hazard Codes | F,Xi |
Risk Statements | 11-19-36-36/37/38 |
Safety Statements | 16-26-33-7/9-37/39 |
RIDADR | UN 1234 3/PG 2 |
OEB | A |
OEL | TWA: 1000 ppm (3100 mg/m3) |
WGK Germany | 1 |
RTECS | PA8750000 |
F | 21 |
Autoignition Temperature | 459 °F |
TSCA | Yes |
HS Code | 2911 00 00 |
HazardClass | 3 |
PackingGroup | II |
Hazardous Substances Data | 109-87-5(Hazardous Substances Data) |
Toxicity | LD50 orally in Rabbit: 6653 mg/kg |
IDLA | 2,200 ppm [10% LEL] |
Product Application of DimethoxymethaneCAS#109-87-5
Dimethoxymethane (Methylal) is a valuable extraction solvent for pharmaceutical products and a stable, inexpensive solvent for Grignard reactions. Methylal is stable under alkaline and mild acidic conditions. Its dissolving ability is stronger than ether, acetone, and methanol and azeotrope can dissolve nitrocellulose with high nitrogen content. Dimethoxymethane is mainly used in the production of anion-exchange resins, and also as solvents and special fuels.
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