Cryolite is an uncommon mineral salt of sodium, fluoride and aluminum that was first discovered on the west coast of Greenland. The supply was depleted by 1987, and synthetic cryolite is now produced from the common mineral fluorite. Cryolite is used at very high application rates of 5-30 kg/ha to control Lepidoptera and Coleoptera on certain fruits, vegetables and citrus. 92% of total cryolite applied in the U.S. is used on grapes in California.An odorless white solid or powder. Mp: 1291°C. Density: 2.95 g cm-3. Dust irritates the eyes and skin; inhaled dust irriates the nose, mouth and lungs. Insoluble in water. Synthesized by fusion of sodium fluoride and aluminum fluoride as a electrolyte in the reduction of alumina to aluminum metal. Occurs in nature as the mineral cryolite. Aqueous suspensions of powdered sodium aluminum fluoride are used as insecticides.
cryolite Chemical Properties |
Melting point | 1012 |
Boiling point | decomp |
density | 2.9 g/mL at 25 °C(lit.) |
refractive index | 1.338 |
storage temp. | 2-8°C |
form | Colorless, crystalline solid |
Odor | Odorless |
Merck | 13,2634 |
InChI | InChI=1S/Al.6FH.3Na/h;6*1H;;;/q+3;;;;;;;3*+1/p-6 |
InChIKey | REHXRBDMVPYGJX-UHFFFAOYSA-H |
SMILES | [Na+].[Na+].[Na+].[Al-3](F)(F)(F)(F)(F)F |
CAS DataBase Reference | 15096-52-3(CAS DataBase Reference) |
EPA Substance Registry System | Cryolite (15096-52-3) |
Safety Information |
Hazard Codes | T,N |
Risk Statements | 20/22-48/23/25-51/53-20 |
Safety Statements | 22-37-45-61 |
OEB | B |
OEL | TWA: 2.5 mg/m3 [*Note: The REL also applies to other inorganic, solid fluorides (as F).] |
RIDADR | UN 3077 9/PG 3 |
WGK Germany | 1 |
RTECS | BD0075000 |
TSCA | TSCA listed |
HazardClass | 9 |
HS Code | 2826300000 |
Storage Class | 6.1C - Combustible acute toxic Cat.3 |
Hazard Classifications | Acute Tox. 4 Inhalation |
Hazardous Substances Data | 15096-52-3(Hazardous Substances Data) |
Product Application of cryolite CAS#15096-52-3
Cryolite is commonly used as an electrolyte for aluminum electrolysis. Alumina is dissolved in molten cryolite is used to dissolve alumina during aluminium processing.
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