Chromium(VI) oxide CAS#1333-82-0
CAS Number: 1333-82-0
Chemical Formula: CrO3
Synonyms:
Chrormic trioxide
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)
Appearance: Red-purple Solid
Chromium(VI) oxide CAS#1333-82-0
Chromium hydroxide (Cr2O(OH)4) is a bright bluish-green pigment prepared by the calcinations of bichromate with boric acid at 500°C. The mass during cooling is hydrolyzed with water, which yields the hydrate.
Chromium(VI) oxide Chemical Properties |
Melting point | 196 °C (dec.)(lit.) |
Boiling point | 330 °C |
bulk density | 900kg/m3 |
density | 2.7 |
vapor pressure | 0Pa at 25℃ |
Fp | 250°C |
storage temp. | Store below +30°C. |
solubility | 1.667g/l |
pka | -0.61[at 20 ℃] |
form | macroporous |
color | Reddish-violet |
Specific Gravity | 2.7 |
PH | <1 (100g/l, H2O, 20℃) |
Water Solubility | Highly soluble |
FreezingPoint | 170~172℃ |
Sensitive | Hygroscopic |
Merck | 14,2235 |
crystal system | Nogata |
Space group | Ama2 |
Lattice constant | a/nmb/nmc/nmα/oβ/oγ/oV/nm30.57430.85570.47899090900.2353 |
Exposure limits | ACGIH: TWA 0.0002 mg/m3; STEL 0.0005 mg/m3 (Skin) |
Stability: | Stable. Strong oxidizer. Reacts with most organic material in a violent and often explosive fashion. Moisture sensitive. |
InChI | 1S/Cr.3O |
InChIKey | WGLPBDUCMAPZCE-UHFFFAOYSA-N |
SMILES | O=[Cr](=O)=O |
CAS DataBase Reference | 1333-82-0(CAS DataBase Reference) |
NIST Chemistry Reference | Chromium trioxide(1333-82-0) |
EPA Substance Registry System | Chromium(VI) trioxide (1333-82-0) |
Safety Information |
Hazard Codes | O,T+,N,T |
Risk Statements | 45-46-9-24/25-26-35-42/43-48/23-50/53-62-8 |
Safety Statements | 53-45-60-61-36/37/39-28-26-22 |
OEB | E |
OEL | TWA: 0.0002 mg/m3 (8-hours) |
RIDADR | UN 1463 5.1/PG 2 |
WGK Germany | 3 |
RTECS | GB6650000 |
TSCA | TSCA listed |
HazardClass | 5.1 |
PackingGroup | II |
HS Code | 28191000 |
Storage Class | 5.1A - Strongly oxidizing hazardous materials |
Hazard Classifications | Acute Tox. 2 Inhalation |
Hazardous Substances Data | 1333-82-0(Hazardous Substances Data) |
Toxicity | LD50 oral (rat) 80 mg/kg |
IDLA | 15 mg Cr(VI)/m3 |
Product Application Of Chromium(VI) oxide CAS#1333-82-0
Chromium(VI) oxide is widely used in chromium electroplating, and as protective coatings in corrosion/oxidation resistance of metals. It is also employed in CDs and DVDs. It is useful as an oxidant in Jones oxidation in acetic acid or acetone. It is used in the oxidation of primary alcohols into carboxylic acids, and secondary alcohols into ketones. With phosphoric acid, it is used as a stripping agent for anodic coatings of all types and in the production of syntheric rubies.
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