Fumaric acid CAS#110-17-8

  • CAS Number: 110-17-8

  • Chemical Formula: C4H4O4

  • Synonyms:

    • ACIDUM FUMARICUM

    • RARECHEM AL BO 0142

    • TRANS-1,2-ETHYLENTRICARBOXYLIC ACID

    Appearance: White Powder

  • MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)



Product Details

Fumaric acid CAS#110-17-8

Fumaric acid is an important kind of organic chemical raw materials as well as the intermediate of fine chemical products. Meanwhile, it is also an important kind of derivatives of maleic anhydride, being widely used in food, coatings, resins and plasticizers. In the food industry, fumaric acid, used as souring agent, can be applied to soft drinks, western-style wine, cold drinks, fruit juice concentrate, canned fruit, pickles and ice cream. As an acidic substance used as solid beverage gas production agent, it has excellent bubble durability with delicate product organization.
Fumaric acid has been used as a food acidulant since 1946. As a food additive, it is used as an acidity regulator and can be denoted by the E number E297. Chemically it is an unsaturated dicarbonic acid and is part of the citric acid cycle.
Fumaric acid is a common food additive included in many processed foods to keep them stable and to add tartness. The substance has a more sour flavor than citric acid, another common food additive. Fumaric acid occurs naturally in fumitory, bolete mushrooms, lichen and Iceland moss. As an additive, fumaric acid is produced synthetically, mainly from malic acid from apples. Fumaric acid as an additive is regulated under the Codex Alimentarius General Standard for Food Additives (GSFA), a collection of internationally recognized standards.The U.S. Food and Drug Administration considers it safe.

Fumaric acid Chemical Properties

Melting point 

298-300 °C (subl.) (lit.)

Boiling point 

137.07°C (rough estimate)

density 

1.62

vapor pressure 

1.7 mm Hg ( 165 °C)

refractive index 

1.5260 (estimate)

FEMA 

2488 | FUMARIC ACID

Fp 

230 °C

storage temp. 

Store below +30°C.

solubility 

95% ethanol: soluble0.46g/10 mL, clear, colorless

pka

3.02, 4.38(at 25℃)

form 

Fine Crystalline Powder

color 

White

PH

3.19(1 mM solution);2.57(10 mM solution);2.03(100 mM solution);

Odor

odorless

Odor Type

odorless

biological source

synthetic

explosive limit

40%

Water Solubility 

0.63 g/100 mL (25 ºC)

Merck 

14,4287

JECFA Number

618

BRN 

605763

Stability:

Stable at room temperature. Decomposes at around 230 C. Incompatible with strong oxidizing agents, bases, reducing agents. Combustible.

Cosmetics Ingredients Functions

BUFFERING

InChIKey

VZCYOOQTPOCHFL-OWOJBTEDSA-N

LogP

-4.02 at 20℃

CAS DataBase Reference

110-17-8(CAS DataBase Reference)

NIST Chemistry Reference

Fumaric acid(110-17-8)

EPA Substance Registry System

Fumaric acid (110-17-8)


Safety Information

Hazard Codes 

Xi

Risk Statements 

36

Safety Statements 

26

RIDADR 

UN 9126

WGK Germany 

1

RTECS 

LS9625000

Autoignition Temperature

375 °C

TSCA 

Yes

HS Code 

29171900

Hazardous Substances Data

110-17-8(Hazardous Substances Data)

Toxicity

LD50 orally in Rabbit: 9300 mg/kg LD50 dermal Rabbit 20000 mg/kg


Product Application of Fumaric acid CAS#110-17-8


  1. Fumaric acid is used for the production of unsaturated polyester resin. This kind of resin is characterized by excellent resistance to chemical corrosion as well as heat resistance; the copolymer of fumaric acid and vinyl acetate is a kind of excellent adhesive. Its copolymer with styrene copolymer is the raw material for the manufacture of glass fiber. The plasticizer of the fumaric acid is non-toxic and can be applied to the vinyl acetate latex contact with food. This product is the intermediate of pharmaceutical and optical bleaching agents and other fine chemicals. Neutralization of fumaric acid with sodium carbonate can generate sodium fumarate ([17013-01-3]), and then replaced with ferrous sulfate to get iron fumarate, being the drug Fersamal used for the treatment of small red blood cell anemic. The product, as a food additive-sourness agent, used in soft drinks, fruit sugar, jelly, ice cream with most of them used in combination with sourness agent, citric acid. The monosidum salt made from the reaction between fumaric acid and sodium hydroxide can also used as sour seasoning, also used as the intermediate of synthetic resin and mordant.
    2. Fumaric acid is included in many dairy-based products. These include dairy drinks such as chocolate milk, cocoa, eggnog, condensed milk and whey protein beverages. It also may be added to clotted cream, milk and cream powders and milk and cream analogues (substitutes). Fumaric acid is added to cheese products, including processed cheese and cheese substitutes. Dairy-based desserts, such as pudding, flavored yogurt, sherbet and sorbet may include fumaric acid as well. Dairy fat spreads and blended spreads can include fumaric acid, and so can preserved eggs and egg-based desserts such as custard.
    3. Some processed and packaged foods have fumaric acid added to them to help stabilize them and enhance their flavor. For example, many processed meats, such as bacon and canned meats, have added fumaric acid. Frozen seafood, smoked meats and the edible casings around sausages might also have fumaric acid added to them. Fermented, canned, dried and processed fruits and vegetables can contain the food additive as well. Rice cakes and other precooked rice foods, dried or preserved eggs, mustard, vinegar, cider, wine and other alcoholic beverages are additional examples of foods that might contain fumaric acid.

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